Adiabatic Thermal Decomposition of 1,1-diamino-2,2-dinitroethylene
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摘要: 采用加速量热仪（ARC）研究了1,1-二氨基-2,2-二硝基乙烯的绝热分解过程，得到了绝热条件下1,1-二氨基-2,2-二硝基乙烯的温度、压力随时间的变化曲线，以及自加热温升速率随温度、时间的变化曲线，根据测试数据计算出分解反应动力学参数：表观活化能为354.76kJ/mol，指前因子为1.49×1023min-1。
Abstract: The adiabatic decomposition of 1,1-diamino-2,2-dinitroethylene has been studied by an accelerating rate calorimeter(ARC). Temperature, pressure of 1,1-diamino-2,2-dinitroethylene on adiabatic thermal condition versus time curves, and self-heating rate versus temperature and time curves were obtained respectively. The kinetic parameters such as apparent activation energy Ea=354.76kJ/mol and pre-exponential factor A=1.49×1023min-1 were obtained according to test data.
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在线发布日期: 2020-12-15
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